It doesn't work that way. #13 nozzle for 10 gpms would be 4000 psi. When I tie my two machines together, my psi is 2500 because my 5.5 gpm machine is 2500 and when tying together you get the lower psi of the two. Straight nozzle calculations are based on 4000 psi. EX: a 4 gpm machine rated at 4000 psi uses a #4 nozzle, a 4 gpm machine rated at 3500 uses a 4.5 nozzle, a 4 gpm machine rated at 3000 psi uses a #5 nozzle. 10 gpms at 2500 psi uses a #13 nozzle.
The #13 is just the orifice size not gpms. The only time it matches up with the gpms, is when your are dealing with 4000 psi.
http://www.pressureparts.com/nozzlecalculator.aspx/