This is commercial hot water sidewalk cleaning, even then you don't need caustic most of the time, I would not use it on that sidewalk but that is just me, I have other cleaning methods/solutions I use for commercial sidewalk cleaning. Most of those window/door frames are aluminum but painted dark, when you see some in shopping centers that are bare aluminum and spray that solution on them, you will be handing over your commercial insurance policy over to the PM or Owner so they can have a company come out and buff out all the damage you just did because you did not know what you were doing, just following someone's advice from the internet and did not have a clue on what damage can happen from using Caustic.
Not trying to be mean here but you need to do a lot more reading and understand these chemicals before just going out and buying whatever because someone said so. You are not at another person's level of experience or knowledge yet so don't do most of what people on the internet say until you have more knowledge/experience under your belt.
Put that bag of caustic into another clear plastic bag for safety and secure it then put it up into storage up high where children and adults will not ever touch it as it can cause very bad permanent damage to skin, eyes and all other body parts at any time. Then once you have more knowledge and experience and have a need for that kind of chemical when you are doing greasy drive thru's, dumpster pads and that kind of stuff, then bring out the caustic, wear the proper ppe and then use that chemical, until then, keep it out of reach of everyone for safety.
As for the church, get some SH (not ever caustic), into a 5 gallon bucket, add in your soap, start downstreaming, once the contaminants are gone, take the soap hose out of the bucket and start rinsing or you can have another bucket with water to rinse out the injector as these need to be rinsed out after the job is done or at the end of the day. I rinse them out before the job is over and they last me a while this way. The SH will eat up the injectors over time, it is just how it is but they will go bad a lot faster if you don't rinse them out with water.
I like to use the same nozzles for applying soap and rinsing, I just have to go back to the trailer to pull the soap hose out of the bucket and put it into a bucket of water, just my personal preference and this helps my injector last a long time.
That is how I wash houses and how I would wash that church, no problem.
Now go git r done.